刘振
发布时间:2024-01-04   访问次数:13128   作者:


姓名:刘振

职务:副教授

电话:021-64253364

手机:13816993351

电子邮件:liuzhen@ecust.edu.cn

 

教育背景:

     2000.09~2004.06 郑州大学8858cc永利皇宫登录  化学工程与工艺专业 学士学位

     2005.09~2007.06 8858cc永利皇宫登录 硕士在读 (导师,曾作祥教授)

     2007.09~2013.03 8858cc永利皇宫登录 博士学位 (导师,刘柏平教授)

     2009.03~2009.09 瑞士联邦理工学院(ETH) 联合培养 (留学基金委资助,导师,Michele Parrinello教授)

 

工作经历:

      2013.04~2015.05 8858cc永利皇宫登录 师资博士后 (导师,钱锋教授)

      2015.01~2016.12 比利时鲁汶大学(KU Leuven) 博士后 (2014年度博士后国际交流计划派出资助,合作导师,Jeremy Harvey教授)

      2019.10~2020.08 澳大利亚国立大学访问学者 (2019年国家留学基金委公派访问学者项目资助,合作导师,Michelle Coote教授)

      2013.04~至今   8858cc永利皇宫登录 讲师,副教授(2018).


研究方向:

本人以第一/通讯作者在ACS Catalysis、Journal of Catalysis、 Catalysis Science &Technology、《有机化学》和《分子催化》等SCI及中文核心期刊上发表论文140余篇,被引2500余次(H-index:27)。主持了国家自然科学基金面上项目1项,上海市浦江人才计划A类项目1项,博士后国际合作项目1项,企业技术开发项目8项,获得中国专利授权6项,美国专利授权3项。

主要研究方向包括:

乙烯高选择性三聚、四聚催化剂及聚合反应工艺开发。在国家自然科学基金面上项目的资助下,针对乙烯选择性齐聚的关键科学问题,揭示了高选择性乙烯齐聚开关型催化剂的分子机制,提出了高碳α烯烃及聚乙烯副产物的形成机理,构建了乙烯选择性齐聚催化体系的机器学习模型。基于机器学习模型开发了乙烯齐聚性能可调的催化剂体系(CN115424682A)。

二氧化碳高值利用(CO2基聚碳酸酯及多元醇)。在上海市浦江人才计划A类项目资助下,解明了过渡金属催化CO2/C2H4偶联反应机理,特别是含铁、钌等体系在非绝热邻近势能面上进行的双态反应机理,提出了过渡金属催化CO2/C2H4偶联反应副产物的抑制方法,合成了一系列新型结构的NHC-P配体。该配体与传统的双氮、双膦配体的两步法反应机理不同,NHC-P配体可实现二氧化碳和乙烯经一步反应制备不饱和羧酸盐(CN115959987A),具有良好的工业应用前景。

其他方面,在特种聚酯合成、EVA光伏膜开发、PVB的合成及应用等方向均取得了重要的研究进展和一定的技术成果。

 

近年来发表SCI论文100余篇,被引用2000余次,谷歌学术H-index28i10-index66,部分代表性论文如下:

1. Peng, J.;  Mei, Y.;  Chen, L.;  Zhu, M.; Liu, Z.*, Computer-aided ligand screening to develop polymer-free catalyst in Cr-catalyzed ethylene oligomerization. Journal of Catalysis2024, 429. DOI: 10.1016/j.jcat.2023.115279. (院新闻报道:https://dwz.win/a7yT)

2. Luo, Z.; Peng, J.; Mu, Y.; Sun, L.; Zhu, Z.; Liu, Z.* Design of Cr-PNP catalysts for ethylene tri-/tetramerization assisted by a data-driven approach. Journal of Catalysis2023, 428. DOI: 10.1016/j.jcat.2023.115127.

3.  Peng, J.; Zhu, M.; Chen, L.; Liu, Z.* Unravelling the chain growth mechanism in Cr/NNN-catalysed ethylene oligomerization. Catalysis Science & Technology2023 (封面文章). DOI: 10.1039/d3cy00954h. (RSC公众号推送:https://dwz.win/a7yU)

4.  Liu, Z.; Qiu, P.; Sun, H.; Sun, L.; Zeng, Z.; Liu, Z.* Oxygen effect on the synthesis of vinyl acetate on Pd (100) and Pd/Au (100) surfaces: A periodic DFT study. Molecular Catalysis2023, 547. DOI: 10.1016/j.mcat.2023.113337.

5.  Ding, X.; Mu, Y.; Zhu, Y.; Guo, X.; Liu, K.; Sun, L.; Liu, Z.* Mechanistic insight into the carboxylic derivatives formation from CO2 and ethylene over iron(0)-based catalyst. Molecular Catalysis2023, 541, 113084. DOI: 10.1016/j.mcat.2023.113084.

6.  Zhu, Y.; Mu, Y.; Sun, L.; Zeng, Z.; Liu, Z.* Mechanistic study on the formation of the alkyl acrylates from CO2, ethylene and alkyl iodides over nickel-based catalyst. Phys. Chem. Chem. Phys.2023, 25 (36), 24733-24744. DOI: 10.1039/d3cp02943c.

7.  Guo, X.; Liu, Z.*; Fan, Z.*; Liu, B.* New Insights into the Nature of Ti(II) and Ti(III) Active Sites in the Heterogeneous Ziegler–Natta Catalyst.J Phys Chem C2023, 127 (12), 5720-5730. DOI: 10.1021/acs.jpcc.2c08288.

8.  Guan, Z.; Zhang, J.; Zhou, W.; Zhu, Y.; Liu, Z.*; Zhang, Y.*; Zhang, Y. Mechanistic Details of the Titanium-Mediated Polycondensation Reaction of Polyesters: A DFT Study. Catalysts2023, 13 (10). DOI: 10.3390/catal13101388.

9.  Zhang, H.;  Zhang, Z.;  Cai, Z.*;  Li, M.*; Liu, Z.*, Influence of Silica-Supported Alkylaluminum on Heterogeneous Zwitterionic Anilinonaphthoquinone Nickel and Palladium-Catalyzed Ethylene Polymerization and Copolymerization with Polar Monomers. ACS Catalysis2022, 12(15), 9646–9654. DOI: 10.1021/acscatal.2c02705

10. Guo, X.;  Shao, Y.;  Luo, J.;  Liu, Z.*; Liu, B.*, The atomic defects on the (104) and (110) surfaces of the MgCl2-supported Ziegler-Natta Catalyst: a periodic DFT study. Catalysis Science & Technology2022, 12, 6761-6770. DOI: 10.1039/d2cy01365g

11. Zhong, X. Q.;  Liu, L.;  Guo, X.;  Sun, L.;  Liu, B. P.; Liu, Z.*, Cr/PCCP-catalysed selective ethylene oligomerization: analysis of various conformations and the hemilabile methoxy group. Catalysis Science & Technology 2022, 12, 5586-5596. DOI: 10.1039/d2cy01219g

12. Sun, H.;  Qiu, P.*;  Yang, Y.;  Liu, J.;  Zhang, L.; Liu, Z.*, Molecular insights into the vinyl acetate synthesis on Pd/Au (1 1 1) Surface: Effects of potassium ion. Applied Surface Science 2022, 571, 151297. DOI: 10.1016/j.apsusc.2021.151297

13. Qiu, P.;  Sun, H.*;  Yang, Y.;  Liu, J.; Liu, Z.*, Molecular insights into the effects of N-doping on synthesis of vinyl acetate over carbon-supported zinc acetate. Catalysis Communications2022, 170, 106490. DOI: 10.1016/j.catcom.2022.106490

14. Zhu, Y.;  Guo, X.;  Ding, X.;  Sun, L.;  Zhang, M.; Liu, Z.*, Understanding the acrylates formation from CO2 and ethylene over Ni- and Pd-based catalysts: A DFT study on the effects of solvents, methyl halides, and ligands. Molecular Catalysis2022, 518, 112108. DOI: 10.1016/j.mcat.2021.112108

15. Wang, J.;  Liu, C.;  Cao, L.;  Xiong, Y.;  Ye, J.;  Liu, Z.*; Cheng, R.*, Theoretical investigation of mechanism and ligand effects on half-sandwich iridium complexes for direct reductive amination. Molecular Catalysis 2022, 517, 112050. DOI: 10.1016/j.mcat.2021.112050

16. Zeng, F.;  Guo, X.;  Sun, L.*;  He, X.;  Zeng, Z.; Liu, Z.*, Non-isothermal crosslinking of ethylene vinyl acetate initiated by crosslinking agents: kinetic modelling. RSC Advances2022, 12 (24), 15623-15630. DOI: 10.1039/d2ra01994a

17. Guo, X.;  Cui, L.;  Yi, J.;  Liu, Z.*; Liu, B.*, Understanding the Role of Sulfonyl Amine Donors in Propylene Polymerization Using MgCl2-Supported Ziegler–Natta Catalyst. Journal of Physical Chemistry C2022., 126(20), 8655-8666. DOI: 10.1021/acs.jpcc.2c02566

18. Chen, Y.;  Qiu, P.;  Sun, H.;  Sun, L.; Liu, Z.*, Mechanistic aspects of the Pd(OAc)n (n=1–3) catalyzed ethylene acetoxylation: A density functional theory study. Applied Organometallic Chemistry2022. 36(10), e6860. DOI:10.1002/aoc.6860

19. Wang, Z.;  Liu, L.;  Ma, X.;  Liu, Y.;  Mi, P.;  Liu, Z.*; Zhang, J.*, Effect of an additional donor on decene formation in ethylene oligomerization catalyzed by a Cr/PCCP system: a combined experimental and DFT study. Catalysis Science & Technology 2021, 11 (13), 4596-4604.

20. Zou, C., Yang L., Zhang L., Liu C., Ma Y., Song G., Liu Z.*, Cheng R.*  and Ye J.* Enantioselective Vinylogous Conia-Ene Reaction Catalyzed by a Disilver(I)/Bisdiamine Complex. ACS Catalysis, 2021, 11(12): 6865-6871.

21. Liu, L.;  Liu, Z.*;  Cheng, R.;  He, X.; Liu, B.*, Ligand-Induced Product Switching between 4-Methyl-1-pentene and 2-Methyl-1-pentene in Bis(imino)pyridine/V(III)-Catalyzed Propylene Dimerization: Cossee–Arlman Versus Metallacycle Mechanism. Organometallics 2021, 40 (11), 1682-1691.

22. Liu, K.;  Liu, Z.*;  Cheng, R.;  He, X.; Liu, B.*, Mechanistic study of vanadium-modified and sulfation-modified Phillips catalyst. Molecular Catalysis 2021, 513, 111777.

23. Liu, K.;  Liu, Z.*;  Cheng, R.;  He, X.; Liu, B.*, Mechanistic Studies of Reduction and Initiation over the Vanadium-Oxide Polyethylene Catalyst. Journal of Physical Chemistry C 2021, 125 (4), 2393-2402.

24. Guo, X.;  Cui, L.;  Wang, Y.;  Yi, J.;  Sun, J.;  Liu, Z.*; Liu, B.*, Mechanistic Study on Effect of Electron Donors in Propylene Polymerization Using the Ziegler–Natta Catalyst. Journal of Physical Chemistry C 2021, 125 (16), 8533-8542.

 

代表性项目

1.2023企业技术开发项目,名称:《乙烯三聚催化体系小试制备技术开发》

2.2023企业技术开发项目,名称:《乙烯选择性齐聚合成线性α-烯烃》

3.2023企业技术开发项目,名称:《黄精寡糖和PROVTA 2.0作用信号通路的理论研究》

4.2022企业技术开发项目,名称:《高纯度2,6-萘二甲酸小试技术开发》

5.2022企业技术开发项目,名称:《2-甲基-6-乙酰基萘技术开发》

6.2021 国家自然科学基金,名称:《基于机器学习的乙烯选择性齐聚催化剂设计与开发》

7.2018 上海市浦江人才项目,名称:《CO2/不饱和烃制备羧酸及衍生物催化体系的分子设计》

8.2016 企业合作项目,名称:《丙烯聚合过程关键组分作用机理研究与分子设计》

9.2014 企业合作项目,名称:《高活性低分子量聚异丁烯的开发研究》

10.2013 国家自然科学基金,名称:《电子自旋交叉对铬系催化烯烃聚合反应的拟实研究》

11.2013 博士后基金,名称:《铬系催化乙烯齐聚、聚合反应中电子自旋交叉的基础研究》





 
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